Direct Observation of a Li‐ionic Space‐Charge Layer Formed at an Electrode/Solid‐Electrolyte Interface

When two different materials come into contact, mobile carriers redistribute at the interface according to their potential difference. Such a charge redistribution is also expected at the interface between electrodes and solid electrolytes. The redistributed ions significantly affect the ion conduction through the interface. Thus, it is essential to reveal the actual distribution of the ionic carriers and their potential to improve ion conduction. We succeeded in visualizing the ionic and potential profiles in the charge redistribution layer, or space‐charge layer (SCL), formed at the interface between a Cu electrode and Li‐conductive solid electrolyte using phase‐shifting electron holography and spatially resolved electron energy‐loss spectroscopy. These electron microscopy techniques clearly showed the Li‐ionic SCL, which damped from 1.3 V with 10‐nm distance from the interface. These techniques would contribute to the development of next‐generation electrochemical devices.

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