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Τρίτη 17 Οκτωβρίου 2017

Purported fragile-to-Arrhenius crossover in squalane [Physical Sciences]

Jadhao and Robbins (1) claim to have discovered a crossover from Vogel–Fulcher–Tammann (VFT) to Arrhenius in squalane occurring at a viscosity of μ=1,000 Pa⋅s using extrapolation of the simple Eyring equation to the limiting low-shear viscosity from nonequilibrium molecular dynamic simulation at high shear rates. Stickel et al. (2) introduced...

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