A "golden fullerene" Au32 cluster has been synthesized with amido and phosphine ligands as the protecting agents. Single crystal X‐ray structural analysis reveals that this gold nanocluster [Au32(Ph3P)8(dpa)6] (SbF6)2 (Hdpa = 2, 2'‐dipyridylamine) has a stable pseudo‐Ih Au328+ core with S6 symmetry, which features an Au12@Au20 Keplerate cage co‐protected by Ph3P and dpa ligands. Quantum chemical studies elucidate the nature of the special stability of this cluster and suggest that it is electronically stabilized via metal‐ligand interaction.
from A via a.sfakia on Inoreader http://bit.ly/2DWiWJZ
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Medicine by Alexandros G. Sfakianakis,Anapafseos 5 Agios Nikolaos 72100 Crete Greece,00302841026182,00306932607174,alsfakia@gmail.com,