The enantioselective first total synthesis of actinorhodin (1) is described, featuring (1) dual benzyne reactions en route to the monomer, (2) trans‐selective installation of the side chain, and (3) the regioselective oxidative dimerization.
from A via a.sfakia on Inoreader http://bit.ly/2MIh1Ni
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Medicine by Alexandros G. Sfakianakis,Anapafseos 5 Agios Nikolaos 72100 Crete Greece,00302841026182,00306932607174,alsfakia@gmail.com,